Publications

2017

Pimenta, V., Sathiya, M., Batuk, D., Abakumov, A.M., Giaume, D., Cassaignon, S., Larcher, D. and Tarascon, J.-M., Synthesis of Li-rich NMC: a comprehensive study, Chemistry of Materials, 2017, accepted

Vaccarelli, O., Rousse, G., Saul, A. and Radkte, G., Magnetic dimerization in the frustrated spin ladder Li2Cu2O(SO4)2, Physical Review B, 2017, 96, 180406R

Assat, G., Iadecola, A., Delacourt, C., Dedryvère, R. and Tarascon, J.-M., Decoupling cationic-anionic redox processes in a model Li-rich cathode via operando X-ray absorption spectroscopy, Chemistry of Materials, 2017, accepted

Rousse, G., Ahouari, H., Pomjakushin, V., Tarascon, J.-M., Recham, N. and Abakumov, A.M., Denticity and mobility of the carbonate groups in AMCO3F fluorocarbonates: a study on KMnCO3F and high temperature KCaCO3F polymorph, Inorganic Chemistry, 2017, accepted

Verger, L., Dargaud, O., Chasssé, M., Trcera, N., Rousse, G. and Cormier, L., Journal of Cultural Heritage, 2017, accepted

Rousse, G., Ahouari, H., Pomjakushin, V., Tarascon, J.-M., Recham N. and Abakumov, A.M., Denticity and mobility of the carbonate groups in AMCO3F fluorocarbonates: A study on KMnCO3F and high temperature KCaCO3F polymorph, Inorganic Chemistry, 2017

Verger, L., Dargaud, O., Chassé, M., Trcera, N., Rousse, G. and Cormier, L., Synthesis, properties and uses of chromium-based pigments from the Manufacture de Sèvres, Journal of Cultural Heritage, 2017

Hong, W.T., Stoerzinger, K.A., Lee, Y.-L., Giordano, L., Grimaud, A., Johnson, A.M., Hwang, J., Crumlin, E.J., Yang, W. and Shao-Horn, Y., Charge transfer energy dependent oxygen evolution reaction mechanisms for perovskites oxides, Energy and Environmental Science, 2017, 10, 2190-2200.

Bellin, C., Mafety, A., Narayana, C., Giura, P., Rousse, G., Itié, J.-P., Polian, A., Saitta, A.M. and Shukla, A, Disorder-order phase transition at high pressure in ammonium fluoride, Physical Review B, 2017, 96, 094110

Lutz, L., Alves Dalla Corte, D., Chen, Y., Batuk, D., Johnson, L.R., Abakumov, A., Yate, L., Azacate, E., Bruce, P., Tarascon, J.-M. and Grimaud, A., The role of the electrode surface in Na-air batteries: insights in electro-chemical product formation and chemical growth of Na-O2, Advanced Energy Materials, 2017

Parant, H., Muller, G., LeMercier, T., Tarascon, J.-M., Poulin, P. and Colin, A., Flowing suspension of carbon black with high electronic conductivity for flow applications: Comparison between carbon black and exhibition of specific aggregation of carbon particles, Carbon, 2017, 119, 10-20

Sathiya, M., Thomas, J., Pimenta, Gopalan, R. and Tarascon, J.-M., Dual stabilization and sacrificial effect of Na2CO3 for increasing capacities of Na-ion cells based on P2-NaxMO2 electrodes, Chemistry of Materials, 2017, 29, 5948-5956

Yang, C., Laberty-Robert, C., Batuk, D., Cibin, G., Chadwick, A., Pimenta, V., Yin, W., Zhang, L. Tarascon, J.-M. and Grimaud, A, Phosphate ion functionalization of perovskite surfaces for enhanced oxygen evolution reaction, The Journal of Physical Chemistry Letters, 2017, 8, 34663475

Lutz, L., Alves Dalla Corte, D., Tang, M., Salager, E., Deschamps, M., Grimaud, A., Johnson, L., Bruce, P. and Tarascon, J.-M., Role of electrolyte anions in the Na-O2 battery: implications for NaO2 solvation and the stability of the sodium solid electrolyte interphase in glyme-ethers, Chemistry of Materials, 2017, 29, 8652-8656

Blazquez-Alcover, I., Rousse, G., Alves Dalla Corte, D., Badot, J.C., Grimaud, A., Rozier, P.  and Tarascon, J.-M., Improving ionic conductivity by Mg-doping of A2SnO3 (A= Li+, Na+), Solid State Ionics, 2017, 308, 16-21

Jacquet, Q., Perez, A., Batuk, D., Van Tendeloo, G., Rousse, G. and Tarascon, J.-M., The Li3RuyNb1-yO4 (0 < y < 1) system: structural diversity and Li insertion and extraction capabilities, Chemistry of Materials, 2017, 29, 5331-5343

Yang, C., Fontaine, O., Tarascon, J.-M. and Grimaud, A., Chemical recognition of active oxygen species on the surface of oxygen evolution reaction electrocatalysts, Angewandte Chemie International Edition, 2017

Yang, C. and Grimaud, A., Factors controlling the redox activity of oxygen in perovskites: from theory to application for catalytic reactions, Catalysts, 2017, 7(5), 149

Verger, L., Dargaud, O., Rousse, G., Cotte, M. and Cormier, L., The stability of gahnite doped with chromium pigments in glazes from the French manufacture of Sèvres, Journal of the American Ceramic Society,  2017, 100, 80-95

Rousse, G., Rodriguez-Carvajal, J, Giacobbe, C., Sun, M., Vaccarelli, O. and Radtke, G., Low-temperature structural transition in the quasi-one-dimensional spin 1/2 compound Li2Cu2O(SO4)2, Physical Review B., 2017, 95, 144103

N’Goc, H.L.T., Mouafo, L.D.N., Etrillard, C., Torres-Pardo, A., Dayen, J.-F., Rano, S., Rousse, G., Laberty-Robert, C., Calbet, J.G., Drillon, M., Sanchez, C., Doudin, B. and Portehault, D., Surface-driven magnetotransport in perovskite nanocrystals, Advanced Materials, 2017, 1604745

Petit, S., Gode, T., Thomas, C., Dzwigaj, S., Millot, Y.., Brouri, D., Krafft, J.-M., Rousse, G., Laberty-Robert, C. and Costentin, G., Incorporation of vanadium into the framework of hydroxyapatites: importance of the vanadium content and pH conditions during the precipitation step, Phys. Chem. Chem. Phys., 2017, 19, 9630

Huan, T.N., Rousse, G., Zanna, S., Lucas, I.T., Xu, X., Menguy, N., Mougel V. and Fontecave, M., A dendritic nanostructured copper oxide electrocatalyst for the oxygen evolution reaction, Angewandte Chemie International Edition, 2017, 56, 4792-4796

Ngoc Huan, T., Simon, P., Rousse, G., Génois, I., Artero, V. and Fontecave, M., Porous dendritic copper: an electrocatalyst for highly selective CO2 reduction to formate in water/ionic liquid electrolyte, Chemical Science, 2017, 8, 742

Huan, T.N., Ranjbar, N., Rousse, G., Sougrati, M., Zitolo, A., Mougel, V., Jaouen, V. and Fontecave, M., Electrochemical reduction of CO2 catalyzed by Fe-N-C materials: a structure-selectivity study, ACS Catalysis, 2017, 7, 1520-1525

Gomez, G.A., Brusau, E.V., Kaczmarek, A.M., Mellot-Draznieks, C., Sacanell, J., Rousse, G., Van Deun, R., Sanchez, C., Narda, G.E. and Soler Illia, G.J.A.A, Flexible ligand-based lanthanide three-dimensional metal-organic frameworks with tunable solid-state photoluminescence and OH-solvent-sensing properties, European Journal of Inorganic Chemistry, 2017, 2321-2331

Pearce, P.E., Perez, A.J., Rousse, G., Saubanère, M., Batuk, D., Foix, D., Abakumov, A.M., Van Tendeloo, G., Doublet, M.-L. and Tarascon, J.-M., Evidence for Anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2O3, Nature Materials, 2017, DOI:10.1038/nmat4864

Zhang, L., Batuk, D., Chen, G. and Taracon, J.-M., Electrochemically activated MnO as a cathode material for sodium-ion batteries, Electrochemistry Communications, 2017, 77, 81-84

Lander, L., Rousse, G., Batuk, D., Colin, C.V., Alves Dalla Corte, D. and Tarascon, J.-M., Synthesis, Structure, and electrochemical properties of K-based sulfates K2M2(SO4)3 with M = Fe and Cu, Inorganic Chemistry, 2017, DOI:10.1021/acs.inorgchem.6b02526

Zhang, L., Chen, G., Berg, E. J. and Tarascon, J.-M., Triggering the in situ electrochemical formation of high capacity cathode material from MnO, Advanced Energy Materials, 2017, DOI:10.1002/aenm.201602200

Grimaud, A. Batteries: activating lithium source at the positive, News and Views, Nature Energy, 2, 17003, 2017

Grimaud, A., Diaz-Morales, O., Han, B., Hong, W.T., Lee, Y.-L., Giordano, L., Stoerzinger, K., Koper, M.T. and Shao-Horn, Y. Activating lattice oxygen redox reactions in metal oxides to catalyze oxygen evolution, Nature Chemistry, accepted, 2017 DOI: 10.1038/nchem.2695

Yin, W., Grimaud, A., Lepoivre, F., Yang, C. and Tarascon, J.-M., Chemical vs electrochemical formation of Li2CO3 as a discharge product in Li-O2/CO2 batteries by controlling the superoxide intermediate, Journal of Physical Chemistry Letters, 8(1), 214-222, 2017

2016

M. R. Palacín, P. Simon, J.-M. Tarascon, Nanometarials for Electrochemical Energy Storgae: the good and the bad. Acta Chim. Slov. 2016, 63, 417–423.

B. Zhang, F. Kang, J.-M. Tarascon, J.-K. Kim, Recent Advances in Electrospun Carbon Nanofibers and their Application in Electrochemical Energy Storage. Prog. Mater. Sci. 2016, 76, 319–380.

M. Sun, G. Rousse, D. D. Corte, M. Saubanère, M.-L. Doublet, J.-M. Tarascon, A Fully Ordered Triplite, LiCuSO4F. Chem. Mater. 2016, 28, 1607–1610.

M. Sun, G. Rousse, M. Saubanère, M.-L. Doublet, D. Dalla Corte, J.-M. Tarascon, A2VO(SO4)2 (A = Li, Na) as Electrodes for Li-ion and Na-ion Batteries. Chem. Mater. 2016, 28, 6637–6643.

A. J. Perez, D. Batuk, M. Saubanère, G. Rousse, D. Foix, E. McCalla, E. J. Berg, R. Dugas, K. H. W. van den Bos, M.-L. Doublet, D. Gonbeau, A.M. Abakumov, G. Van Tendeloo, J.-M. Tarascon, Strong Oxygen Participation in the Redox Governing the Structural and Electrochemical Properties of Na-rich Layered Oxide Na2IrO3. Chem. Mater. 2016, 28, 8278–8288.

L. Lander, M. Reynaud, J. Rodríguez-Carvajal, J.-M. Tarascon, G. Rousse, Magnetic Structures of Orthorhombic Li2M(SO4)2 (M = Co, Fe) and LixFe(SO4)2 (x = 1, 1.5) Phases. Inorg. Chem. 2016, 2, 2–11.

F. Strauss, G. Rousse, M. T. Sougrati, D. A. Dalla Corte, M. Courty, R. Dominko, J.-M. Tarascon, Synthesis, Structure, and Electrochemical Properties of Na3MB5O10 (M = Fe, Co) Containing M(2+) in Tetrahedral Coordination. Inorg. Chem. 2016, 55, 12775–12782.

D. Foix, M. Sathiya, E. McCalla, J.-M. Tarascon, D. Gonbeau, X-ray Photoemission Spectroscopy Study of Cationic and Anionic Redox Processes in High-Capacity Li-ion Battery Layered-Oxide Electrodes. J. Phys. Chem. C 2016, 120, 862–874.

L. Lutz, W. Yin, a. Grimaud, D. Alves Dalla Corte, M. Tang, L. Johnson, E. Azaceta, V. Sarou-Kanian, a. J. Naylor, S. Hamad, et al., J. Phys. Chem. C 2016, 120, 20068–20076.

B. Zhang, G. Rousse, D. Foix, R. Dugas, D. A. D. Corte, J.-M. Tarascon, Adv. Mater. 2016, 28, 9824–9830.

B. Zhang, C. M. Ghimbeu, C. Laberty, C. Vix-Guterl, J.-M. Tarascon, Adv. Energy Mater. 2016, 6, 1501588.

M. Saubanère, E. McCalla, J.-M. Tarascon, M.-L. Doublet, Energy Environ. Sci. 2016, 9, 984–991.

F. Strauss, G. Rousse, D. Alves Dalla Corte, M. Ben Hassine, M. Saubanère, M. Tang, H. Vezin, M. Courty, R. Dominko, J.-M. Tarascon, Phys. Chem. Chem. Phys. 2016, 18, 14960–9.

L. Lander, M. Reynaud, J. Carrasco, N. a Katcho, C. Bellin, A. Polian, B. Baptiste, G. Rousse, J.-M. Tarascon, Phys. Chem. Chem. Phys. 2016, 18, 14509–19.

R. Shivaramaiah, L. Lander, G. P. Nagabhushana, G. Rousse, J.-M. Tarascon, A. Navrotsky, Chemphyschem 2016, 17, 3365–3368.

G. Assat, C. Delacourt, D. A. D. Corte, J.-M. Tarascon, J. Electrochem. Soc. 2016, 163, A2965–A2976.

R. Dugas, B. Zhang, P. Rozier, J. M. Tarascon, J. Electrochem. Soc. 2016, 163, A867–A874.

R. Dugas, a. Ponrouch, G. Gachot, R. David, M. R. Palacin, J. M. Tarascon, J. Electrochem. Soc. 2016, 163, A2333–A2339.

F. Lepoivre, A. Grimaud, D. Larcher, J.-M. Tarascon, J. Electrochem. Soc. 2016, 163, A923–A929.

F. Lepoivre, D. Larcher, J.-M. Tarascon, J. Electrochem. Soc. 2016, 163, A2791–A2796.

B. Mirvaux, N. Recham, J. Miot, M. Courty, S. Bernard, O. Beyssac, C. Davoisne, M. Sougrati, a. Demortière, F. Guyot, et al., J. Electrochem. Soc. 2016, 163, A2139–A2148.

M. Tułodziecki, J.-M. Tarascon, P.-L. Taberna, C. Guéry, J. Electrochem. Soc. 2016, 163, D355–D365.

B. Zhang, R. Dugas, G. Rousse, P. Rozier, A. M. Abakumov, J.-M. Tarascon, Nat. Commun. 2016, 7, 10308.

M. Tang, V. Sarou-Kanian, P. Melin, J.-B. Leriche, M. Ménétrier, J.-M. Tarascon, M. Deschamps, E. Salager, Nat. Commun. 2016, 7, 13284.

A. Grimaud, W. T. Hong, Y. Shao-Horn, J.-M. Tarascon, Nat. Mater. 2016, 15, 121–6.

C. P. Grey, J. M. Tarascon, Nat. Mater. 2016, 16, 45–56.

A. Grimaud, J.-M. Tarascon, Actual. Chim. 2016, 408-409, 24–29.

A. Grimaud, A. Demortiere, M. Saubanere, W. Dachraoui, M. Duchamp, M. Doublet, J.-M. Tarascon, Nat. Energy 2016, 2, 16189.

G. Rousse, G. Radtke, Y. Klein, H. Ahouari, Dalton Trans. 2016, 45, 2536–48.

G. Rousse, J. Rodríguez-Carvajal, Dalton Trans. 2016, 45, 14311–9.

P. Borghetti, E. Meriggio, G. Rousse, G. Cabailh, R. Lazzari, J. Jupille, J. Phys. Chem. Lett. 2016, 7, 3223–8.

L. Verger, O. Dargaud, G. Rousse, M. Cotte, L. Cormier, J. Am. Ceram. Soc. 2016, 8, 1–8.

L. Verger, O. Dargaud, G. Rousse, E. Rozsályi, A. Juhin, D. Cabaret, M. Cotte, P. Glatzel, L. Cormier, Phys. Chem. Miner. 2015, 43, 33–42.

2015

Ahouari, H. et al. Synthesis, structure and electrochemical properties of metal malonate Na2M(H2C3O4)2·nH2O (n = 0, 2) compounds and comparison with oxalate Na2M2(C2O4)3·2H2O compounds. Solid State Sci. 42, 6–13 (2015).

Ahouari, H. et al. Unraveling the Structure of Iron(III) Oxalate Tetrahydrate and Its Reversible Li Insertion Capability. Chem. Mater. 27, 1631–1639 (2015).

Chotard, J.-N. et al. Discovery of a Sodium-Ordered Form of Na 3 V 2 (PO 4 ) 3 below Ambient Temperature. Chem. Mater. 27, 5982–5987 (2015).

Demir-Cakan, R., Morcrette, M. & Tarascon, J.-M. Use of ion-selective polymer membranes for an aqueous electrolyte rechargeable Li-ion–polysulphide battery. J. Mater. Chem. A 3, 2869–2875 (2015).

Hong, W. T. et al. Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis. Energy Environ. Sci. 8, 1404–1427 (2015).

Lander, L. et al. Structural, electrochemical and magnetic properties of a novel KFeSO 4 F polymorph. J. Mater. Chem. A 3, 19754–19764 (2015).

Larcher, D. & Tarascon, J.-M. Towards greener and more sustainable batteries for electrical energy storage. Nat. Chem. 7, 19–29 (2015).

McCalla, E. et al. Reversible Li-Intercalation through Oxygen Reactivity in Li-Rich Li-Fe-Te Oxide Materials. J. Electrochem. Soc. 162, A1341–A1351 (2015).

McCalla, E. et al. Novel Complex Stacking of Fully-Ordered Transition Metal Layers in Li 4 FeSbO 6 Materials. Chem. Mater. 27, 1699–1708 (2015).

McCalla, E. et al. Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li4FeSbO6. J. Am. Chem. Soc. 137, 4804–14 (2015).

McCalla, E. et al. Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries. Science 350, 1516–21 (2015).

Morales-García, A. et al. Combining experiments and computations to understand the intercalation potential and redox mechanism for A 2Ti3O7 (A=Li, Na). MRS Proc. 1740, mrsf14–1740–z08–06 (2015).

Radha, A. V., Lander, L., Rousse, G., Tarascon, J. M. & Navrotsky, A. Thermodynamic stability and correlation with synthesis conditions, structure and phase transformations in orthorhombic and monoclinic Li 2 M(SO 4 ) 2 (M = Mn, Fe, Co, Ni) polymorphs. J. Mater. Chem. A 3, 2601–2608 (2015).

Rozier, P. et al. Anionic redox chemistry in Na-rich Na2Ru1−ySnyO3 positive electrode material for Na-ion batteries. Electrochem. commun. 53, 29–32 (2015).

Rozier, P. & Tarascon, J. M. Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges. J. Electrochem. Soc. 162, A2490–A2499 (2015).

Sathiya, M. et al. Origin of voltage decay in high-capacity layered oxide electrodes. Nat. Mater. 14, 230–8 (2015).

Sun, M. et al. Li 2 Cu 2 O(SO 4 ) 2 : a Possible Electrode for Sustainable Li-Based Batteries Showing a 4.7 V Redox Activity vs Li + /Li 0. Chem. Mater. 27, 3077–3087 (2015).

Tao, L., Rousse, G., Sougrati, M. T., Chotard, J.-N. & Masquelier, C. (NH 4 ) 0.75 Fe(H 2 O) 2 [BP 2 O 8 ]·0.25H 2 O, a Fe 3+ /Fe 2+ Mixed Valence Cathode Material for Na Battery Exhibiting a Helical Structure. J. Phys. Chem. C 119, 4540–4549 (2015).

Yao, K. P. C. et al. Solid-state activation of Li 2 O 2 oxidation kinetics and implications for Li–O 2 batteries. Energy Environ. Sci. 8, 2417–2426 (2015).

Zhang, L., Tarascon, J.-M., Sougrati, M. T., Rousse, G. & Chen, G. Influence of relative humidity on the structure and electrochemical performance of sustainable LiFeSO 4 F electrodes for Li-ion batteries. J. Mater. Chem. A 3, 16988–16997 (2015).

2014

Johnson, L. et al. The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li–O2 batteries. Nat. Chem. 1–9 (2014). doi:10.1038/nchem.2101

Demir-Cakan, R., Morcrette, M., Leriche, J.-B. & Tarascon, J.-M. An aqueous electrolyte rechargeable Li-ion/polysulfide battery. J. Mater. Chem. A 2, 9025 (2014).

Clark, J. M. et al. High voltage sulphate cathodes Li2M(SO4)2 (M = Fe, Mn, Co): atomic-scale studies of lithium diffusion, surfaces and voltage trends. J. Mater. Chem. A 2, 7446 (2014).

Eames, C., Clark, J. M., Rousse, G., Tarascon, J. & Islam, M. S. Lithium Migration Pathways and van der Waals E ff ects in the LiFeSO 4 OH Battery Material. Chem. Mater. 26, 3672–3678 (2014).

G. Rousse, B. Baptiste, G. L. Crystal Structures of Li6B4O9 and Li3B11O18 and Application of the Dimensional Reduction Formalism to Lithium Borates. Inorg. Chem. 53, 6034–6041 (2014).

Lander, L. et al. Synthesis and Electrochemical Performance of the Orthorhombic Li 2 Fe(SO 4 ) 2 Polymorph for Li-Ion Batteries. Chem. Mater. 26, 4178–4189 (2014).

Melot, B. C. et al. Chemical and Structural Indicators for Large Redox Potentials in Fe-Based Positive Electrode Materials. ACS Appl. Mater. Interfaces 6, 10832–10839 (2014).

Radha, A. V., Subban, C. V., Sun, M. L., Tarascon, J. M. & Navrotsky, A. Possible correlation between enthalpies of formation and redox potentials in LiMSO 4 OH (M = Co, Fe, Mn), Li-ion polyanionic battery cathode materials. J. Mater. Chem. A 2, 6887–6894 (2014).

Reynaud, M., Rodríguez-Carvajal, J., Chotard, J.-N., Tarascon, J.-M. & Rousse, G. Magnetic structure and properties of orthorhombic Li 2 Ni(SO 4 ) 2 : A possible magnetoelectric material. Phys. Rev. B 89, 104419 (2014).

Rousse, G. & Tarascon, J. M. Sulfate-Based Polyanionic Compounds for Li-Ion Batteries: Synthesis, Crystal Chemistry, and Electrochemistry Aspects. Chem. Mater. 26, 394–406 (2014).

Salager, E., Sarou-kanian, V., Sathiya, M., Tang, M. & Leriche, J. Solid-State NMR of the Family of Positive Electrode Materials Li 2 Ru 1 −ySnyO3 for Lithium_Ion Batteries. Chem. Mater. 26, 7009–7019 (2014).

Subban, C. V., Rousse, G., Courty, M., Barboux, P. & Tarascon, J.-M. Polymorphism in Bi2(SO4)3. Solid State Sci. 38, 25–29 (2014).

Sun, M. et al. An Oxysulfate Fe 2 O(SO 4 ) 2 Electrode for Sustainable Li-Based Batteries. J. Am. Chem. Soc. 136, 12658–12666 (2014).

Tobias, G. et al. On a new FeOF polymorph: Synthesis and stability. Solid State Sci. 38, 55–61 (2014).